Buried interface engineering drives advances in tin-lead perovskite solar cell efficiency
by Simon Mansfield
Sydney, Australia (SPX) Dec 20, 2024
A team led by Prof. Meng Li from Henan University’s School of Nanoscience and Materials Engineering has unveiled an innovative approach to overcoming stability and efficiency challenges in tin-lead (Sn-Pb) perovskite solar cells. The researchers’ work focuses on optimizing the buried hole-selective interface using a specially designed self-assembled material, offering major implications for single-junction and tandem solar cell technologies.
Tin-lead perovskites are valued for their narrow bandgap properties, which position them as key materials for producing high-efficiency solar cells. However, energy level mismatches and degradation at the buried interface have constrained both their performance and long-term stability. Addressing these issues, Prof. Meng’s team designed a boronic acid-anchored hole-selective contact material, 4-(9H-carbazole-9-yl)phenylboronic acid (4PBA).
Compared to conventional materials, 4PBA demonstrated superior stability and compatibility at the substrate surface. Its high adsorption energy of -5.24 eV and significant molecular dipole moment (4.524 D) improved energy level alignment between the substrate and perovskite layer, facilitating efficient charge extraction. Additionally, the interface engineered using 4PBA improved perovskite crystallization and substrate contact, reducing defects and non-radiative recombination.
These advancements enabled Sn-Pb perovskite solar cells incorporating 4PBA to achieve a power conversion efficiency (PCE) of 23.45%. The material’s reduced corrosiveness also mitigated the degradation effects typically caused by PEDOT:PSS, a widely used hole-transport material, enhancing chemical stability and storage durability. The cells retained 93.5% of their initial efficiency after 2,000 hours of shelf storage.
“This approach offers a practical path to enhancing both the efficiency and stability of Sn-Pb perovskite solar cells, addressing energy level mismatches and interfacial stability concerns,” the research team commented.
The findings provide a foundation for advancing efficient and stable Sn-Pb perovskite solar cells and highlight the importance of interface engineering in next-generation photovoltaic technologies.
Research Report:Buried Hole-Selective Interface Engineering for High-Efficiency Tin-Lead Perovskite Solar Cells with Enhanced Interfacial Chemical Stability
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